The origin of high bicarbonate and fluoride concentrations in waters of the Main Ethiopian Rift Valley, East African Rift system

Thermal waters in the Main Ethiopian Rift Valley are characterized by high Na, bicarbonate and fluoride concentrations, and near-neutral to alkaline pH. Sodium, bicarbonate and fluoride are positively correlated in the waters. The principal reason for the bicarbonate in the area is the high rate of carbon dioxide outgassing. This, combined with acid volcanics, geothermal heating, low Ca and low salinity, is also one of the causes of high fluoride in this part of the active volcanic zone of the East African Rift. Evaporative concentration is responsible for the high salinity, alkalinity and fluoride in the closed-basin lakes of the region. The waters are undersaturated with respect to fluorite and anhydrite. Calcium tends to be fixed in Ca bearing minerals such as calcite and epidote, which are abundant in the system. Hence, it appears that fluoride is a mobile component in acid volcanic geothermal systems.