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Publication Details
AFRICAN RESEARCH NEXUS
SHINING A SPOTLIGHT ON AFRICAN RESEARCH
chemistry
Co(II), Cd(II), Hg(II) and U(VI)O
2
complexes of o-hydroxyacetophenone[N-(3-hydroxy-2-naphthoyl)] hydrazone: Physicochemical study, thermal studies and antimicrobial activity
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Volume 97, Year 2012
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Description
The o-Hydroxy acetophenone [N-(3-hydroxy-2-naphthoyl)] hydrazone (H 2o-HAHNH) has been prepared and its structure is confirmed by elemental analysis, IR, 1H NMR and 13C NMR spectroscopy. It has been used to produce diverse complexes with Co(II), Cd(II), Hg(II) and U(VI)O2 ions. The isolated complexes have been investigated by elemental analysis, magnetic measurements, molar conductivity, thermal (TG, DTG) and spectral (1H NMR, 13C NMR, IR, UV-visible, MS) studies. Infrared spectra suggested H2o-HAHNH acts as a bidentate and/or tridentate ligand. The electronic spectrum of [Co(Ho-HAHNH)2] complex as well as its magnetic moments suggesting octahedral geometry around Co(II) center. The TG analyses suggest high stability for most complexes followed by thermal decomposition in different steps. Moreover, the kinetic and thermodynamic parameters (Ea, A, ΔH, ΔS and ΔG) for the different decomposition steps of the [Co(Ho-HAHNH)2] and [Cd(Ho-HAHNH)2] complexes were calculated using the Coats-Redfern and Horowitz-Metzger methods. Moreover, the antibacterial and antifungal activities of the isolated compounds were studied using a wide spectrum of bacterial and fungal strains. © 2012 Elsevier B.V. All rights reserved.
Authors & Co-Authors
Zaky, Rania Ramadan
Egypt, Mansoura
Faculty of Science
Yousef, Tarek A.
Egypt, Mansoura
Faculty of Science
Egypt, Asiut
Ministry of Justice
Ibrahim, Kamal M.
Egypt, Mansoura
Faculty of Science
Statistics
Citations: 67
Authors: 3
Affiliations: 2
Identifiers
Doi:
10.1016/j.saa.2012.05.086
ISSN:
13861425