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AFRICAN RESEARCH NEXUS

SHINING A SPOTLIGHT ON AFRICAN RESEARCH

chemistry

Rhizophoraceae alkaloids. Part II. Gerrardine

Journal of the Chemical Society C: Organic Chemistry, Year 1967

The mass spectrum of gerrardine, C11H19NO 2S4, showed a molecular ion species corresponding to (C8H14NOS2)+, and Raney nickel desulphurisation gave a compound, C10H22O2, m. p. 33°, considered as decane-2,9-diol. The structure for the alkaloid is deduced as 1-methyl-2,5-bis-(4-hydroxy-1,2-dithiolan-3-yl)pyrrolidine.

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