Improvement in Fresh, Mechanical and Microstructural Properties of Fly Ash- Blast Furnace Slag Based Geopolymer Concrete By Addition of Nano and Micro Silica

In this study, the effect of nano-silica (NS) and silica fume (SF) on workability, setting time, compressive strength and microstructural properties of fly ash-ground granulated blast furnace slag (FA-GGBFS) based geopolymer concrete (GPC) is investigated. Five mixtures of each containing 0.5%, 1.0%, 1.5%, 2.0% and 2.5% NS and SF are prepared for this investigation. The optimum GPC mixture with NS resulted in compressive strength of 63 MPa and the SF modified GPC achieved a compressive strength of 59.59 MPa after 28 days of outdoor temperature curing (Avg. temp. 31.4℃). The hardened concrete samples are analyzed through X-ray diffraction (XRD), X-ray fluorescence (XRF), field emission scanning electron microscope (FESEM), Fourier transform infrared spectroscopy (FTIR), and petrographic examination, for the better understanding of geopolymer mineralogy, mechanism and microstructure. Results indicate that both NS and SF facilitated a higher degree of geopolymerization, leading to the densification of the geopolymer matrix which led to the improvement of the properties of FA-GGBFS based GPC.