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Publication Details
AFRICAN RESEARCH NEXUS
SHINING A SPOTLIGHT ON AFRICAN RESEARCH
chemistry
Employing imine macrocycle ligand in the atom transfer radical polymerization of methyl methacrylate
Journal of Macromolecular Science - Pure and Applied Chemistry, Volume 42 A, No. 8, Year 2005
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Description
Imine macrocycle M1 was successfully used in conjunction with CuBr as a catalytic system in the atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA). The role of the reaction conditions was clearly observed. Such reaction conditions were found to be the molar ratios of the reactants, the chosen initiating systems, and some additional ambient conditions (e.g. temperature, solvent). MMA homopolymers were successively prepared via ATRP by using benzhydrylbromide, diethylmethylbromomalonate initiating systems under the appropriate reaction conditions. Definite well-known structures of the formed polymers were unambiguously identified with 1H NMR. Copyright © Taylor & Francis, Inc.
Authors & Co-Authors
Amin, Amal T.
Egypt, Giza
National Research Centre
Ayoub, Magdy M.H.
Egypt, Giza
National Research Centre
El-Ghaffar, Mahmoud A.
Egypt, Giza
National Research Centre
Rieger, Bernhard
Germany, Ulm
Universität Ulm
Statistics
Citations: 4
Authors: 4
Affiliations: 2
Identifiers
Doi:
10.1081/MA-200065910
ISSN:
10601325