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Publication Details
AFRICAN RESEARCH NEXUS
SHINING A SPOTLIGHT ON AFRICAN RESEARCH
earth and planetary sciences
Multiple sulfur isotope evidence for surface-derived sulfur in the Bushveld Complex
Earth and Planetary Science Letters, Volume 337-338, Year 2012
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Description
The Rustenberg Layered Suite of the Bushveld Complex originated in the mantle, but is characterized by variably radiogenic strontium, neodymium, lead and osmium initial isotope ratios and more elevated δ 18O values than expected from a partial melt of primitive mantle. It is not clear whether Bushveld magmas assimilated material from the crust, or whether they were instead generated from an eclogitic mantle source that contained crustal material. Here we report the Δ 33S of fifteen whole-rock and sulfide separate samples from both the Main and Critical Zones of the Bushveld, including the UG2 Chromitite and the Merensky Reef. All samples have positive Δ 33S values (0.11±0.02‰, 1σ) and δ 34S values (2.2±0.6‰, 1σ). Non-zero Δ 33S is fundamentally a surface process. Since high-temperature processes are not known to produce significant change in Δ 33S, the positive Δ 33S indicates that the Bushveld sulfur contains a sedimentary or surface-derived component. The homogeneity of Δ 33S values for this suite of samples contrasts with the heterogeneity displayed by strontium, neodymium, lead and osmium initial isotope ratios of the Bushveld and requires that the sulfur contamination occurred prior to the emplacement of the Bushveld in the upper crust. Possible sources of contamination include lower crust and sub-continental lithospheric mantle. Limited multiple sulfur isotopic measurements of these reservoirs exist; more work needs to be done to constrain whether they contain surface-derived sulfur with non-zero Δ 33S, and if they do, whether the concentrations and isotopic compositions of these reservoirs can explain the measured Δ 33S of the Bushveld. © 2012 Elsevier B.V.
Authors & Co-Authors
Penniston-Dorland, Sarah C.
United States, College Park
University of Maryland, College Park
Mathez, Edmonda A.
United States, New York
American Museum of Natural History
Wing, Boswell A.
Canada, Montreal
Université Mcgill
Canada, Montreal
Université du Québec à Montréal
Farquhar, James
United States, College Park
University of Maryland, College Park
Kinnaird, Judith Ann
South Africa, Johannesburg
University of the Witwatersrand
Statistics
Citations: 50
Authors: 5
Affiliations: 5
Identifiers
Doi:
10.1016/j.epsl.2012.05.013
ISSN:
0012821X
Research Areas
Genetics And Genomics