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Publication Details
AFRICAN RESEARCH NEXUS
SHINING A SPOTLIGHT ON AFRICAN RESEARCH
Synthesis and complexing properties of a double-calix[4]arene crown ether
Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, Volume 13, No. 2, Year 1992
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Description
Treatment of p-tert-butylcalix[4]arene with tetraethyleneglycol ditosylate in the presence of potassium carbonate in acetonitrile afforded the first example of a double-calixcrown (1) in 52% yield. The double-calixcrown (1) was shown to form 1: 1 complexes with potassium and rubidium picrates in the solid state and in solution in chloroform. The stability constants of the alkali complexes have been determined in acetonitrile, as well as the phase transfer parameters from water to dichloromethane. © 1992 Kluwer Academic Publishers.
Authors & Co-Authors
Asfari, Zouhair
Unknown Affiliation
Abidi, Rym
Unknown Affiliation
Arnaud-Neu, Françoise
Unknown Affiliation
Vicens, Jacques E.
Unknown Affiliation
Statistics
Citations: 88
Authors: 4
Identifiers
Doi:
10.1007/BF01053640
ISSN:
15731111
Research Areas
Environmental