Spontaneous combustion of coal seams in the Witbank and Sasolburg coalfields, South Africa, was studied in order to determine if toxic chemical elements and compounds are being mobilised into the environment. Samples of the minerals forming on the surface of coal seams, and gases escaping from vents, were analysed to verify the presence of these elements and compounds. Gas temperature measurements at coal-fire vents range from 34 °C to 630 °C. The coal-fire gas minerals (CFGM) identified included sulphur compounds and salammoniac. X-ray diffraction (XRD) studies of CFGM by-products confirmed the presence of mascagnite ((NH4)2SO4), illite ((Al,Si)4O10[(OH)2,H2O]) letovicite ((NH4)3H(SO4)2), phlogopite (KMg3(AlSi3)O10(F,OH)2), titanium dioxide (TiO2), barite (BaSO4), iron sulphate (FeSO4), gypsum (CaSO4·2H2O) and silicate. An unknown and unclassified sulphur-nitrogen-chlorine CFGM was also identified. The minerals are interpreted to have formed by condensation or sublimation; several may be alteration products. Other heavy elements found in the CFGM's are mercury, arsenic, lead, zinc, and copper. Arsenic and mercury were the major elements of potential environmental significance found accumulating around coal-fire vents. Relatively high concentrations of toluene, benzene and xylene were found in the gas collected at both Witbank and Sasolburg coalfields. Benzene, toluene and xylenes are known to possess carcinogenic proprieties. Thirty-two aliphatic compounds were detected, as well as halogenated compounds including bromomethane, iodomethane and trichloromethane in low concentrations, and dichloromethane and chloromethane in high concentrations. The highest concentrations of halogenated compounds were measured for gas samples from the Witbank coalfield. High concentrations of carbon monoxide, carbon dioxide, and methane were also detected. The nature of the risks to human health and the environment of most of the compounds in gas and CFGM by-products of spontaneous combustion at the Witbank and Sasolburg coalfields are unknown and merit investigation. Fires caused by spontaneously combusted coal are pervasive in the coalfields and the health consequences of exposure to hazardous elements are a serious risk. It would be prudent to undertake an environmental impact assessment of these elements in order to determine the extent of their impact on mine workers and the environment in the Witbank and Sasolburg coalfields. © 2007 Elsevier B.V. All rights reserved.
