Influence of air-cooled slag on physicochemical properties of autoclaved aerated concrete

Lime and sand in autoclaved aerated concrete (AAC) were replaced by air-cooled slag (AS). The compressive strength and the type and nature of the hydration products were studied for samples autoclaved at 8 bar for different periods of times: 2, 6, 12 and 24 h. The hydration reactions were monitored by determining free-lime contents and combined water. The types of the hydration products were investigated using XRD and SEM/EDX. Slag substitutions for sand and lime up to 50% enhance the compressive strength, especially at short curing times (2 and 6 h). The optimum strength is obtained by 50% AS substitution for low-lime mixes (10% CaO) and 30% AS substitution for high-lime mixes (25% CaO). In high-lime mixes containing up to 30% AS, the initially formed fibrous calcium-rich CSH was changed to needle-like and lath-like 1.1 nm tobermorite. In low-lime mixes with AS-substitution, tobermorite appears at 2 h processing time with grass-like silica-rich CSH around quartz particles. © 2004 Elsevier Ltd. All rights reserved.