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Publication Details
AFRICAN RESEARCH NEXUS
SHINING A SPOTLIGHT ON AFRICAN RESEARCH
chemistry
Solution processing route to multifunctional titania thin films: Highly conductive and photcatalytically active Nb:TiO
2
Advanced Functional Materials, Volume 24, No. 32, Year 2014
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Description
This paper reports the synthesis of highly conductive niobium doped titanium dioxide (Nb:TiO2) films from the decomposition of Ti(OEt)4 with dopant quantities of Nb(OEt)5 by aerosol-assisted chemical vapor deposition (AACVD). Doping Nb into the Ti sites results in n-type conductivity, as determined by Hall effect measurements. The doped films display significantly improved electrical properties compared to pristine TiO2 films. For 5 at.% Nb in the films, the charge carrier concentration was 2 × 1021 cm-3 with a mobility of 2 cm2 V-1 s-1. The corresponding sheet resistance is as low as 6.5 Ω sq-1 making the films suitable candidates for transparent conducting oxide (TCO) materials. This is, to the best of our knowledge, the lowest reported sheet resistance for Nb:TiO 2 films synthesized by vapour deposition. The doped films are also blue in colour, with the intensity dependent on the Nb concentration in the films. A combination of synchrotron, laboratory and theoretical techniques confirmed niobium doping into the anatase TiO2 lattice. Computational methods also confirmed experimental results of both delocalized (Ti 4+) and localized polaronic states (Ti3+) states. Additionally, the doped films also functioned as photocatalysts. Thus, Nb:TiO2 combines four functional properties (photocatalysis, electrical conductivity, optical transparency and blue colouration) within the same layer, making it a promising alternative to conventional TCO materials. Solution processing of Nb:TiO2 has presented many challenges to the materials community. Nb:TiO2 made by solution processing has been consigned to sensor/catalysis applications. Here, a solution route is presented to highly conductive and photocatalytically active Nb:TiO2 films. A blue color is observed for the niobium doped films with XPS and computational methods showing a stable localized Ti3+ state at the anatase surface compared to the bulk. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Authors & Co-Authors
Bhachu, Davinder S.
United Kingdom, London
University College London
Sathasivam, Sanjayan S.
United Kingdom, London
University College London
United Kingdom, London
Bio Nano Consulting
Sankar, Gopinathan Girija
United Kingdom, London
University College London
Scanlon, David O.
United Kingdom, London
University College London
Cibin, Giannantonio
United Kingdom, Didcot
Diamond Light Source
Carmalt, Claire J.
United Kingdom, London
University College London
Parkin, Ivan P.
United Kingdom, London
University College London
Watson, Graeme W.
Ireland, Dublin
Trinity College Dublin
Bawaked, Salem M.
Saudi Arabia, Jeddah
King Abdulaziz University
Obaid, Abdullah Yousif
Saudi Arabia, Jeddah
King Abdulaziz University
Al-Thabaiti, Shaeel Ahmed
Saudi Arabia, Jeddah
King Abdulaziz University
Basahel, Sulaiman Nassir
Saudi Arabia, Jeddah
King Abdulaziz University
Statistics
Citations: 95
Authors: 12
Affiliations: 5
Identifiers
Doi:
10.1002/adfm.201400338
ISSN:
1616301X
e-ISSN:
16163028