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Publication Details
AFRICAN RESEARCH NEXUS
SHINING A SPOTLIGHT ON AFRICAN RESEARCH
chemical engineering
[PdA (IPr*) (cinnamyl)Cl]: An efficient pre-catalyst for the preparation of tetra-ortho-substituted biaryls by Suzuki-Miyaura cross-coupling
Chemistry - A European Journal, Volume 18, No. 15, Year 2012
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Description
The bigger the better: The new well-defined [Pd(IPr*)(cin)Cl] pre-catalyst is described (see scheme). This complex proves to be highly active in the Suzuki-Miyaura cross-coupling for the synthesis of tetra-ortho- substituted biaryls under mild conditions. IPr* is reported as the largest N-heterocyclic carbene (NHC) to date for [Pd(NHC)(cin)Cl] complexes, explaining the high reactivity observed for this complex in this challenging transformation. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Authors & Co-Authors
Chartoire, Anthony
United Kingdom, St Andrews
University of st Andrews
Lesieur, Mathieu
United Kingdom, St Andrews
University of st Andrews
Falivene, Laura
Italy, Salerno
Università Degli Studi Di Salerno
Slawin, Alexandra M.Z.
United Kingdom, St Andrews
University of st Andrews
Cavallo, Luigi
Italy, Salerno
Università Degli Studi Di Salerno
Saudi Arabia, Thuwal
King Abdullah University of Science and Technology
Cazin, Catherine S.J.
United Kingdom, St Andrews
University of st Andrews
Nolan, Steven Patrick
United Kingdom, St Andrews
University of st Andrews
Statistics
Citations: 152
Authors: 7
Affiliations: 3
Identifiers
Doi:
10.1002/chem.201104009
ISSN:
09476539
e-ISSN:
15213765