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Publication Details
AFRICAN RESEARCH NEXUS
SHINING A SPOTLIGHT ON AFRICAN RESEARCH
chemistry
Electrocatalytic synthesis of hydrogen peroxide on Au-Pd nanoparticles: From fundamentals to continuous production
Chemical Physics Letters, Volume 683, Year 2017
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Description
The electrochemical synthesis of hydrogen peroxide (H2O2) represents a promising alternative to the anthraquinone process, as it combines on-site chemical and electrical production. The design of selective electrocatalysts is challenging and is commonly based on the alloying of elements to generate a synergistic effect and increase activity. In the present work, we report the electrochemical activity of Au-Pd nanoparticles immobilized directly onto an electrode as a model to study H2O2 electrochemical synthesis from fundamentals to continuous production. The impact of composition on the oxygen reduction reaction (ORR), the selectivity, as well as the peroxide reduction and oxidation reactions (PROR) are studied. © 2017 Elsevier B.V.
Authors & Co-Authors
Cherevko, Serhiy
Germany, Dusseldorf
Max-planck-institut Für Eisenforschung Gmbh
Germany, Erlangen
Friedrich-alexander-universität Erlangen-nürnberg
Hutchings, Graham John
United Kingdom, Cardiff
Cardiff University
Mayrhofer, Karl J.J.
Germany, Dusseldorf
Max-planck-institut Für Eisenforschung Gmbh
Germany, Erlangen
Friedrich-alexander-universität Erlangen-nürnberg
Freakley, Simon J.
United Kingdom, Cardiff
Cardiff University
Statistics
Citations: 99
Authors: 4
Affiliations: 4
Identifiers
Doi:
10.1016/j.cplett.2017.01.071
ISSN:
00092614