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Publication Details
AFRICAN RESEARCH NEXUS
SHINING A SPOTLIGHT ON AFRICAN RESEARCH
chemistry
Mechanism and kinetics of dithiobenzoate-mediated RAFT polymerization. I. The current situation
Journal of Polymer Science, Part A: Polymer Chemistry, Volume 44, No. 20, Year 2006
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Description
Investigations into the kinetics and mechanism of dithiobenzoate-mediated Reversible Addition-Fragmentation Chain Transfer (RAFT) polymerizations, which exhibit nonideal kinetic behavior, such as induction periods and rate retardation, are comprehensively reviewed. The appreciable uncertainty in the rate coefficients associated with the RAFT equilibrium is discussed and methods for obtaining RAFT-specific rate coefficients are detailed. In addition, mechanistic studies are presented, which target the elucidation of the fundamental cause of rate retarding effects. The experimental and theoretical data existing in the literature are critically evaluated and apparent discrepancies between the results of different studies into the kinetics of RAFT polymerizations are discussed. Finally, recommendations for further work are given. © 2006 Wiley Periodicals, Inc.
Authors & Co-Authors
Barner-Kowollik, Christopher
Australia, Sydney
Unsw Sydney
Buback, Michael J.
Germany, Gottingen
Georg-august-universität Göttingen
Charleux, Bernadette
France, Paris
Sorbonne Université
Coote, Michelle L.
Australia, Canberra
The Australian National University
Drache, Marco
Germany, Clausthal-zellerfeld
Technische Universität Clausthal
Fukuda, Takeshi
Japan, Kyoto
Kyoto University
Goto, Atsushi
Japan, Kyoto
Kyoto University
Klumperman, Bert
Netherlands, Eindhoven
Technische Universiteit Eindhoven
Lowe, Andrew B.
United States, Hattiesburg
University of Southern Mississippi
McLeary, James B.
South Africa, Stellenbosch
Stellenbosch University
Moad, Graeme
Australia, Melbourne
Csiro Molecular and Health Technologies
Monteiro, Michael J.
Australia, Brisbane
The University of Queensland
Sanderson, Ronald D.
South Africa, Stellenbosch
Stellenbosch University
Tonge, Matthew P.
South Africa, Stellenbosch
Stellenbosch University
Australia, Sydney
The University of Sydney
Vana, Philipp
Germany, Gottingen
Georg-august-universität Göttingen
Statistics
Citations: 357
Authors: 15
Affiliations: 12
Identifiers
Doi:
10.1002/pola.21589
ISSN:
0887624X
e-ISSN:
10990518