Study of the acetaldehyde induced polymerisation of flavan-3-ols by liquid chromatography-ion spray mass spectrometry
Journal of Chromatography A, Volume 752, No. 1-2, Year 1996
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In some fruits, the loss of astringency has been attributed to the insolubilization of recombinated tannins, formed by reaction with acetaldehyde,This route has been investigated by on-line coupling of liquid chromatography with ion spray mass spectrometry (LC-ISP-MS). The results reported herein indicate that LC-ISP-MS can be successfully applied to tannin polymers and is very helpful in their identification. It also allows direct monitoring of the progress of polymerisation reactions. The mechanism of the acetaldehyde-induced polymerisation of flavan-3-ols has thus been demonstrated.