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Publication Details
AFRICAN RESEARCH NEXUS
SHINING A SPOTLIGHT ON AFRICAN RESEARCH
chemical engineering
Cobalt and nitrogen co-doped graphene-carbon nanotube aerogel as an efficient bifunctional electrocatalyst for oxygen reduction and evolution reactions
Catalysts, Volume 8, No. 7, Article 275, Year 2018
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Description
In this study, a low-cost and environmentally friendly method is developed to synthesize cobalt and nitrogen co-doped graphene-carbon nanotube aerogel (Co-N-GCA) as a bifunctional electrocatalyst for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER). The as-prepared Co-N-GCA has a hierarchical meso-and macroporous structure with a high N doping level (8.92 at. %) and a large specific surface area (456 m2 g−1). In an alkaline medium, the catalyst exhibits superior ORR electrocatalytic activity with an onset potential 15 mV more positive than Pt/C, and its diffusion-limiting current density is 29% higher than that of commercial Pt/C. The obtained Co-N-GCA is also highly active toward the OER, with a small overpotential of 408 mV at a current density of 10 mA cm−2. Its overall oxygen electrode activity parameter (∆E) is 0.821 V, which is comparable to most of the best nonprecious-metal catalysts reported previously. Furthermore, Co-N-GCA demonstrates superior durability in both the ORR and the OER, making it a promising noble-metal-free bifunctional catalyst in practical applications for energy conversion and storage. © 2018 by the authors. Licensee MDPI, Basel, Switzerland.
Authors & Co-Authors
Qiao, Xiaochang
China, Guangzhou
Key Laboratory of Fuel Cell Technology of Guangdong Province
China, Dongguan
Dongguan University of Technology
Ji, Shan
China, Jiaxing
Jiaxing University
Liao, Shijun
China, Guangzhou
Key Laboratory of Fuel Cell Technology of Guangdong Province
Statistics
Citations: 22
Authors: 3
Affiliations: 3
Identifiers
Doi:
10.3390/catal8070275
ISSN:
20734344
Research Areas
Environmental