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Publication Details
AFRICAN RESEARCH NEXUS
SHINING A SPOTLIGHT ON AFRICAN RESEARCH
chemical engineering
Preparation, characterisation and activity of an iron/sodalite catalyst for the oxidation of methane to methanol
Topics in Catalysis, Volume 1, No. 1-2, Year 1994
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Description
An iron sodalite catalyst similar to that reported to have good selectivity for the oxidation of methane to methanol by Lyons et al. has been prepared, tested and characterised. In a limited range of temperature at 34 bar total pressure the selectivity of the catalyst to methanol is a little better than that of an empty silica glass reactor. Before reaction, X-ray powder diffraction and Mössbauer spectroscopy confirm the presence of Fe(III) in the sodalite framework. After reaction Mössbauer spectroscopy identifies Fe(II) and also small particles of iron(III) oxide, < 1 μm in size. © 1994 J.C. Baltzer AG, Science Publishers.
Authors & Co-Authors
Catlow, C. R.A.
United Kingdom, London
The Royal Institution of Great Britain
Grimes, Robin
United Kingdom, London
The Royal Institution of Great Britain
Hargreaves, Justin S.J.
United Kingdom, Liverpool
University of Liverpool
Hutchings, Graham John
United Kingdom, Liverpool
University of Liverpool
Pankhurst, Quentin A.
United Kingdom, Liverpool
University of Liverpool
Taylor, Stuart H.
United Kingdom, Liverpool
University of Liverpool
Statistics
Citations: 11
Authors: 6
Affiliations: 2
Identifiers
Doi:
10.1007/BF01379580
ISSN:
10225528