Implementation and evaluation of multivariate analysis for groundwater hydrochemistry assessment in arid environments: A case study of Hajeb Elyoun-Jelma, Central Tunisia

In most arid zones, groundwater (GW) is the major source of domestic, agriculture, drinking, and industrial water. Accordingly, the monitoring of its quality by different techniques and tools is a vital issue. The purpose of this paper is the evaluation of the combination of principal components analysis (PCA) and geostatistics as a technique for (1) identifying the processes affecting the groundwater chemistry of the detrital unconfined Middle Miocene Aquifer (MMA) of the Hajeb elyoun Jelma (HJ) aquifer (Tunisia) and (2) mapping the controlling variables for groundwater quality. This work is based on a limited database recorded in 22 wells tapping the aquifer and unequally distributed in the field. The proposed approach is carried out in two steps. In the first step, the application of PCA revealed that rock-water interaction, agriculture irrigation and domestic effluents could explain 85 % of the observed variability of the chemical GW quality of the MMA. As a result, two new variables are defined: V1 (rock-water interaction influence) and V2 (irrigation and domestic effluent influence). In the second step, the spatial variability of these variables over the extent of the MMA is mapped by applying a kriging interpolation technique. The results of this study suggest that, while both natural and anthropogenic processes contribute to the GW quality of the MMA, natural impacts can be considered as the most important. © 2013 Springer-Verlag Berlin Heidelberg.