Synthesis and evaluation of N,S-compounds as chiral ligands for transfer hydrogenation of acetophenone
Organic and Biomolecular Chemistry, Volume 1, No. 2, Year 2003
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New nitrogen- and sulfur-containing compounds, bicyclic and monocyclic, were prepared and evaluated as ligands in the transfer hydrogenation of acetophenone. Utilising [Ir(COD)Cl]2 as metal precursor the best result, 80% ee, was obtained using a bicyclic sulfoxide ligand.