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Publication Details
AFRICAN RESEARCH NEXUS
SHINING A SPOTLIGHT ON AFRICAN RESEARCH
chemical engineering
Effective and reusable oil/water separation membranes based on modified polysulfone electrospun nanofiber mats
Chemical Engineering Journal, Volume 259, Year 2015
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Description
Membrane technology is the most promising process for oil/water separation operation if the hydrophilicity, fouling and reusability properties could be improved. In this study, novel effective and reusable membrane for oil-water separation process is introduced based on modification of polysulfone (PSF) electrospun nanofiber mats. The modification process was achieved by incorporation of NaOH nanoparticles inside the PSF nanofibers, and formation of a thin layer from a polyamide polymer on the surface of the electrospun mat. Typically, solutions composed of PSF and NaOH (twelve solutions were prepared based on different PSF concentrations; 15, 18 and 20wt%, and various NaOH content; 1.5, 1.7 and 2.5wt%) have been electrospun, then the dried nanofiber mats were treated by m-phenylenediamine and 1,3,5-benzenetricarbonyl chloride to form polyamide thin layer on the surface of the mats. The results indicated that incorporation of NaOH and the formed polyamide could decrease the water contact angle from ~130° to 13° for the nanofiber mats obtained from 20wt% PSF solutions containing 1.7wt% sodium hydroxide. Interestingly, the membrane having the lowest contact angle could separate oil-water mixture for three successive cycles with complete removal of the oil at a relatively high water flux; 5.5m3/m2day. Overall, simplicity of the manufacturing technique, and effectiveness and reusability of the produced nanofiber mats open new avenue for the introduced electrospun mats as promising membranes for the oil-water separation process. © 2014 Elsevier B.V.
Authors & Co-Authors
Obaid, M.
South Korea, Jeonju
Jeonbuk National University
Barakat, Nasser A.M.
South Korea, Jeonju
Jeonbuk National University
Egypt, Minya
Faculty of Engineering
Fadali, Olfat A.
Egypt, Minya
Faculty of Engineering
Motlak, Moaaed
South Korea, Jeonju
Jeonbuk National University
Almajid, Abdulhakim Abdulrahman
Egypt, Minya
Faculty of Engineering
Khalil, Khalil Abdelrazek
Saudi Arabia, Riyadh
King Saud University
Egypt, Aswan
Aswan University
Statistics
Citations: 161
Authors: 6
Affiliations: 4
Identifiers
Doi:
10.1016/j.cej.2014.07.095
ISSN:
13858947
Research Areas
Environmental