Tin Halide Perovskite Films Made of Highly Oriented 2D Crystals Enable More Efficient and Stable Lead-free Perovskite Solar Cells
ACS Energy Letters, Volume 5, No. 6, Year 2020
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Low toxicity and an ideal energy bandgap make two-dimensional (2D) Ruddlesden-Popper tin-based halide perovskites a promising photovoltaic material. However, the disordered crystal orientation and the oxidation of Sn2+ to Sn4+ still need to be addressed. Here, we demonstrate that the annealing of FASnI3 assisted by phenyl ethylammonium chloride enables the formation of more ordered 2D tin-based perovskite crystals oriented vertically. We use in situ synchrotron-based grazing incident X-ray diffraction to correlate the higher crystal orientation to the better device performance. We measured a maximum power conversion efficiency of more than 9%. Furthermore, we demonstrate that the phenyl ethylammonium chloride acts as a barrier layer at the surface of the crystals protecting the tin from the oxidation. Hence, this work paves the way for more efficient and stable lead-free perovskite solar cells.