Enthalpies of formation of the AgCs(NO 3) 2 and Ag 3Cs(NO 3) 4 compounds

Molar solution enthalpies of AgNO 3, CsNO 3, AgCs(NO 3) 2 and Ag 3Cs(NO 3) 4, were measured in pure water at 298.15 K, using different calorimeters. The corresponding molar solution enthalpies at infinite dilution are then used to derive the enthalpies of formation of the AgCs(NO 3) 2 and Ag 3Cs(NO 3) 4 compounds referred to the pure nitrates respectively as -7.34 and -9.33 kJ mol -1. © 2012 Elsevier B.V.